a)PTHH: ZnCl2+2KOH---->Zn(OH)2+2KCl

b)

mZnCl2=204.10100=20,4(g)ZnCl2=204.10100=20,4(g)

nZnCl2=20,4136=0,15(mol)ZnCl2=20,4136=0,15(mol)

nKOH=112.20%56=0,4(mol)KOH=112.20%56=0,4(mol)

=> 0,15/1 <  0,4/1=> KOH dư

Theo pthh, ta có :

nCu(OH)2=nZnCl2=0,15(mol)Cu(OH)2=nZnCl2=0,15(mol)

mCu(OH)2=0,15.98=14,7(g)Cu(OH)2=0,15.98=14,7(g)

c) m dd sau pư=204+112=316(g)

Theo pthh

nKOH=2nZnCl2=0,3(mol)KOH=2nZnCl2=0,3(mol)

C% KOH=

nKCl=2nZnCl2=0,3(mol)KCl=2nZnCl2=0,3(mol)

C% KCl=

nKOH = 0,075 nMgCl2 = 0,05 => MgCl2 dư

2KOH + MgCl2 => 2KCl + Mg(OH)2

=> n Mg(OH)2 = 1/2nKOH = 0,0375

=> m Mg(OH)2 = 2,175 (g)

c% MgCl2 dư = 0,95%

C% KCl = 4,47%

\(a,\left\{{}\begin{matrix}m_{H_2SO_4}=\dfrac{300\cdot9,8\%}{100\%}=29,4\left(g\right)\\m_{BaCl_2}=\dfrac{200\cdot26\%}{100\%}=52\left(g\right)\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}n_{H_2SO_4}=\dfrac{29,4}{98}=0,3\left(mol\right)\\n_{BaCl_2}=\dfrac{52}{208}=0,25\left(mol\right)\end{matrix}\right.\\ PTHH:H_2SO_4+BaCl_2\rightarrow2HCl+BaSO_4\downarrow\)

Vì \(\dfrac{n_{H_2SO_4}}{1}>\dfrac{n_{BaCl_2}}{1}\) nên sau phản ứng \(H_2SO_4\) dư

\(\Rightarrow n_{BaSO_4}=0,25\left(mol\right)\\ \Rightarrow a=m_{BaSO_4}=0,25\cdot233=58,25\left(g\right)\)

\(b,n_{HCl}=2n_{BaCl_2}=0,5\left(mol\right)\\ \Rightarrow m_{CT_{HCl}}=0,5\cdot36,5=18,25\left(g\right)\\ m_{dd_{HCl}}=300+200-58,25=441,75\left(g\right)\\ \Rightarrow C\%_{HCl}=\dfrac{18,25}{441,75}\cdot100\%\approx4,13\%\)

\(a,PTHH:H_2SO_4+BaCl_2\rightarrow BaSO_4\downarrow+2HCl\\ \left\{{}\begin{matrix}m_{H_2SO_4}=\dfrac{300\cdot9,8\%}{100\%}=29,4\left(g\right)\\m_{BaCl_2}=\dfrac{200\cdot26\%}{100\%}=52\left(g\right)\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}n_{H_2SO_4}=\dfrac{29,4}{98}=0,3\left(mol\right)\\n_{BaCl_2}=\dfrac{52}{208}=0,25\left(mol\right)\end{matrix}\right.\)

Vì \(\dfrac{n_{H_2SO_4}}{1}>\dfrac{n_{BaCl_2}}{1}\) nên H₂SO₄ dư

\(\Rightarrow n_{BaSO_4}=n_{BaCl_2}=0,25\left(mol\right)\\ \Rightarrow a=m_{BaSO_4}=0,25\cdot233=58,25\left(g\right)\\ b,n_{HCl}=n_{BaCl_2}=0,25\left(mol\right)\\ \Rightarrow m_{CT_{HCl}}=0,25\cdot36,5=9,125\left(g\right)\\ m_{dd_{HCl}}=300+200-58,25=441,75\left(g\right)\\ \Rightarrow C\%_{HCl}=\dfrac{9,125}{441,75}\cdot100\%\approx2,07\%\)

\(n_{H_2SO_4}=\dfrac{200.19,6}{100.98}=0,4mol\\ CuO+H_2SO_4\rightarrow CuSO_4+H_2O\\ n_{CuSO_4\left(A\right)}=n_{CuO}=n_{H_2SO_4}=0,4mol\\ n_{Cu\left(OH\right)_2}=\dfrac{29,4}{98}=0,3mol\\ CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\\\Rightarrow\dfrac{0,4}{1}>\dfrac{0,3}{1}\Rightarrow CuSO_4.pư.không.hết\)

\(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)

0,3mol        0,6mol                                        0,3mol

\(m_{ddB}=0,4.80+200+0,6.40-29,4=226,6g\\ C_{\%Na_2SO_4\left(B\right)}=\dfrac{0,3.142}{226,6}\cdot100=18,8\%\)

a/

\(n_{Na_2O}=\dfrac{9,3}{62}=0,15\left(mol\right)\)

\(Na_2O+H_2O\rightarrow2NaOH\)

0,15 0,3 (mol)

\(m_{NaOH}=0,3.40=12\left(g\right)\)

\(m_A=90,7+9,3=100\left(g\right)\)

\(C\%_{NaOH}=\dfrac{12}{100}.100\%=12\%\)

b/

m\(_{FeSO_4}=\dfrac{16.200}{100}=32\left(g\right)\)

\(\rightarrow m_{FeSO_4}=\dfrac{32}{152}=\dfrac{4}{19}\left(mol\right)\)

\(2NaOH+FeSO_4\rightarrow Na_2SO_4+Fe\left(OH\right)_2\downarrow\)

bđ: 0,3 \(\dfrac{4}{19}\) 0 0 (mol)

pư: 0,3 0,15 0,15 0,15 (mol)

dư: 0 \(\dfrac{23}{380}\) (mol)

\(m_{Fe\left(OH\right)_2}=0,15.90=13,5\left(g\right)\)

\(m_C=100+200-13,5=286,5\left(g\right)\)

\(m_{Na_2SO_4}=0,15.142=21,3\left(g\right)\)

\(\rightarrow C\%_{Na_2SO_4}=\dfrac{21,3}{286,5}.100\%\approx7,4\%\)

\(m_{FeSO_4\left(dư\right)}=\dfrac{23}{380}.152=9,2\left(g\right)\)

\(\rightarrow C\%_{FeSO_4\left(dư\right)}=\dfrac{9,2}{286,5}.100\%\approx3,2\%\)

Ta có: \(n_{H_2SO_4}=\dfrac{200.19,6\%}{98}=0,4\left(mol\right)\)

\(n_{Cu\left(OH\right)_2}=\dfrac{29,4}{98}=0,3\left(mol\right)\)

PT: \(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)

Dung dịch A gồm: CuSO₄ và H₂SO₄ dư

\(H_2SO_4+2NaOH\rightarrow Na_2SO_4+2H_2O\)

\(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)

Đề có cho dữ kiện gì liên quan đến dd NaOH không bạn nhỉ?